WebTo a 10 mL Schlenk tube equipped with a magnetic stir bar was charged with diarylphosphine oxide1 (0.25 mmol), KF (34.9 mg, 0.6 mmol) and formamide (1 mL) in a glove box. The aryne precursor 2(0.3 mmol) was added to the reaction mixture, then stirred at room temperature for 12 h. WebA mild, reagent-cyanide-free, and efficient synthesis of O-phosphinoyl-protected cyanohydrins from readily available α-substituted malononitriles was realized using …

Organic photoredox catalytic α-C(sp3)–H phosphorylation of …

WebThe straightforward synthesis of α-amino phosphine oxides via three-component reactions involving arynes, formamides and diarylphosphine oxides is disclosed. This … WebSep 7, 2024 · Abstract. A new visible light-mediated photocatalytic decarboxylative oxyphosphorylation of cinnamic acids with diarylphosphine oxides is described. … iman shumpert and teyana taylor

Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of …

WebOct 8, 2024 · It was confirmed by several control experiments that a chiral weak conjugate acid of the chiral bis (guanidino)iminophosphorane, instead of achiral diarylphosphine oxides, directly functioned as the proton source to afford the corresponding product in a highly enantioselective manner in most cases. WebThe copper-catalyzed radical multi-component coupling of maleimides, anilines, and diarylphosphine oxides has been realized, providing the rapid synthesis of a library of … WebApr 4, 2024 · Diarylphosphine oxide Sliver salt Introduction Phosphorus-substituted heterocycles, an important class of organophosphorus compounds, have drawn considerable attention from chemists because they have been widely existed in material chemistry [1], medicinal chemistry [2], as well as chemical intermediates in organic … list of hbse theories